Review of small stationary reformers for hydrogen production. These include steam methane reforming smr, partial oxidation pox, autothermal reforming atr, methanol reforming, ammonia cracking and catalytic cracking of methane. Past hot outlet header issues steammethane reformers have either hot or cold outlet headers to collect the process gas from the outlet of. Reformer hot outlet headers this paper discusses mechanical integrity issues for primary reformer hot outlet headers. Superheater header, with endcaps removed for inspection. Pdf a study of cracking failure of threeway t junctions between inlet manifold and.
The inlet header pigtail failures were at a sharp shoulder on an alloy 800 ht reducer. Steam reforming of methane is a vital unit operation in the manufacture of synthesis gas or syngas. Steam cracking definition and meaning collins english. The mechanism of stress relaxation cracking is known by many names. Several pigtail failures occurred on f901 steam reformer inlet and outlet header from 2007 to 2009 at agriums ammonia plant in redwater, alberta, canada. Introduction the steam reformer is one of the most important and costly. The formation of coke in a typical steam cracker environment is an inevitable and complex phenomenon. Safely operating steam reformers between turnarounds. Most common process used today is however steam reforming and in particular. The hydrogen is produced by steam reforming of methane.
Evaluation of stress relaxation cracking on 800ht pigtails. This paper will discuss the results of an investigation into cracking that occurred on alloy 800h pigtails from a steam reformer furnace. This publication presents a baseline for safe reformer header system operation. The majority of the work he performed was on reformer tube change outs and outlet header replacement on a wide range of steam reformer designs.
On the outlet header, an alloy 800 ht pigtail failed by creep failure after 42,000 hours of service. The outlet transfer line from the reformer is used to generate highpressure usually 650 psig steam. Steam methane reformer furnace outlet manifold component repair. Hydrogen gas steam methane reformer catalyst tube outlet pigtail header nickelironchromium alloys uns n08810 n08811 creep rupture nipping failure investigation risk based inspection approach minimize downtime of production. The outlet header of the steam reformer failed after it has been in service for about 11 years. Steam reforming or steam methane reforming is a chemical synthesis for producing syngas hydrogen and carbon monoxide from hydrocarbons such as natural gas. Steam reformer solutions for steam reformers our products tailormade for your specific requirements the furnace, could rightly been stated, is at the heart of. The combined inlet pressures are adjusted to match the header pressure without energy loss or gain. This publication provides a technical basis that can be used to present a common viewpoint to government and regulatory authorities, ensuring proper application of rules and regulations.
However, in present samples, longitudinal cracks were found on the pigtails. Each reformer tube has a feed inlet at its lower end, an outlet at its upper end, and a catalyst containment zone disposed intermediate its upper and lower ends and contains a charge of a particulate steam reforming catalyst which is insufficient to fill completely the catalyst containment zone. Dictionary grammar blog school scrabble thesaurus translator quiz more resources more from collins. Pigtail nipping leak impingement on refractory and other tubes before nip after nip inlet pigtail header header outlet pigtail x x x x x x nip poisitons 59. Redefining steam methane reformer performance in hydrogen production diane dierking johnson matthey process technologies. At last, dont forget to enhance the power of crystals.
Two of the reformer units were constructed in 1979. Evaluation of stress relaxation cracking on 800ht pigtails of the steam reformer article in journal of failure analysis and prevention 1810 april 2018 with 2 reads how we measure reads. Cold header replacement was planned in 2012, due to severe hot spots occurrences. Steam cracking is the main method of breaking down large molecules of hydrocarbons, in. Equilibrium composition out of a steam reformer at 26 bar with a feed steam to methane ratio of 2. Since the late 1960s, uhde has succeeded in eliminating the use of hot pigtails in the reformer outlet manifold which were a considerable source of failure in steam reforming plants.
The steam methane reformer of ril sez refinery was commissioned in 2009. Ligament cracking in a crmo44 superheater header john. Abb lummus srt ethylene cracking tube, product picture. A tubular reformer furnace is provided with refractory lined outlet headers, inlet headers may be lined said headers being external to the furnace box in order to eliminate excessive thermal growth of the headers, and relatively small diameter unlined tubing is provided for connecting the inlet header with the tubes in order to absorb the differential thermal expansion between the tubes and. Figure 1 shows simple schematic of steam cracking furnace. To ensure a constant mass flow through the plant, the furnace temperature must be raised. It was requested to conduct a failure analysis on damage in the outlet pigtail tubes that occurred in the form of cracks. Over the past 50 years, lummus technology has built more than 200 smr furnaces that produce highpurity gas streams for industrial applications. Ethane, being the simplest feedstock, requires the highest temperature 800 oc 900 c to crack and thus, it utilizes huge amount of energy to operate. Superheater outlet headers, fabricated from crmo44 1cr0. A failure analysis and creep remaining life assessment on hydrogen reformer outlet pigtail tubes in a methanol plant was conducted. Download citation steam methane reformer furnace outlet manifold component repair experience the steam methane reformer of ril sez refinery was commissioned in 2009. This lay predominantly in the circumferential direction in the bottom pair of each set of four ligaments. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states.
Compared to thermal cracking, catalytic cracking occurs at lower temperatures and pressures, is more selective and flexible, and incorporates a catalyst. Us10384183b2 steam methane reformer tube outlet assembly. Page 1 steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. The main purpose of this technology is hydrogen production. The steam methane reformer is widely used in industry. Steam reformer pigtail failures fertilizer services. The reformer effluent gas exits through the transfer line at about 1,400 o f and enters the tube side of a singlepass steam generator. The outlet pigtail was used to transfer the process fluid of the steam reformer which is connected to a manifold header. Special construction of the coils of this furnace guarantee short residence time that why this furnaces callwd srt. Catalytic cracking processes have evolved over the years, and are an exemplary display of che. Because hydrogen needs within various sectors of the cpi are at their highest levels in history, and are continuing to grow, an understanding of this method of hydrogen production and purification can be useful.
Recently we had observed cracking in the ring welding of the bull header to hot header. Optimize production and boost profitability while keeping. The rate of damage accelerates at the onset of cracking. Steam reformer furnaces are used for the production of hydrogen. Reformer furnace outlet collection systems operate under severe service conditions that. Hi this is a quick and dirty on how to use steams formatting system, which, quite frankly, could use a little love headers what is formatting. Strainage cracking of alloy 601 tubes at 600 c iffco. On the outlet header, an alloy 800 ht pigtail failed by creep failure after 42,000 hours.
Because of the pyrolysis reaction, thermally insulating hydrocarbon is deposited on the tube walls, so reducing the effective crosssectional area. More specifically, it relates to an exposed flanged tube outlet of a reformer designed to mitigate metal dusting corrosion, dew point condensationrelated metal fatigue and cracking, and overtemperature induced metal failures such as hydrogen attack. The present work has been focused to find out causes of damaging 12 outlet pigtails of primary steam reformer in the ammonia plant of shiraz petrochemical complex spc after 78. Typical components of syngas outlet header piping systems include. High alloy welds of bull tee on a subheader cracked erection. Process and metallurgical evaluation of outlet pigtails. With great difficulty we were able to repair these cracks. Reformer tubes, cracking tubes, stainless steel manufacturer supplier in china, offering hydrogen production furnace tube header pipe assembly hx61054, no cracks bottom tube support casting hx91016, heatresistant alloy steel bottom tube support casting hx91015 and so on.
The third reformer involved in this incident was constructed in 1987 and put on line in 1988. Steam reforming of propane wolfram demonstrations project. Cracks and possible throughwall failures at pigtail end connections to. In 1999, he joined a reformer tube inspection company, building upon the maintenance expertise he gained and focusing on reformer tube. What are the differences between reforming and cracking in. Aiga 095 16 mechanical integrity of syngas outlet systems. Row of steam reformer tubes pinched tube pinched tube in steam reformer 60. We assume that the propane molar flow rate in the feed stream is 1 mols and that the steampropane molar ratio in the feed stream is 9. It makes things look nice, like look at the header i made right there, it can be used to organize thoughts and to make things look less like walls of text. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane reforming smr. Optimize production and boost profitability while keeping your people safe. A hydrocarbon feedstock is mixed with steam and heated in the presence of a catalyst to produce crude hydrogen which is then purified.
The most common hydrocarbon feed is natural gas, but propane, butane or lpg are also used. Can also get maldistribution due to poor fuel header design. On restart this can crack thereby depositing carbon on the surface of the catalyst. Failure analysis and creep remaining life of hydrogen. The tube material was manufactured to asme sb407 uns n08810 material specifications. Steam cracking cracking furnaces fuel gasoil to other furnaces feedstock dilution steam decoking effluent cracked gas from other furnaces hp steam more pass inlets furnace convection section burnersradiant section more pass outlets demineralized water this diagram is intended to be a representation and should not be viewed as an actual. We have 3220 nicr hot outlet header in our hydrogen reformer. The steam reformer is a two cell design with bottom burners, two rows of catalyst. The material of construction is alloy 800ht, which is an ironnickelchromium alloy. Steam methane reforming smr is the most widely utilized technology for producing hydrogen and synthesis gas from natural gas feedstocks. Extensive ligament cracking after 4 years service 400 starts. Novel reformer technologies such as sorbent enhanced. The header has bull header connection to the cold header. Using the steam property calculator, properties are determined using header pressure and the header specific enthalpy.
The reaction is strongly endothermic consumes heat. This is achieved in a reformer which reacts steam at high temperature and pressure with methane in the presence of a nickel catalyst. In the game, you will become a reformer, who is going to save the world. Creep crack development through the tube wall start. Steammethane reformer furnaces, or smrs, are used in a number of common. From the description, it can be concluded that steam cracking is an energy intensive process. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. Typically, cracks on pigtails occur circumferentially due to high bending stresses in the bends, or at welded connections. Pdf challenges of welding of catalyst tubes and outlet assemblies. Metallurgical failure investigation of cracked steam reformer tubes. China hydrogen production furnace tube header pipe. Mixed feed gas and steam mixed feed preheat prereformer reheat prereformer.
Lower overall steamcarbon ratios provides protection for the main reformer in its most common application today the main benefit comes from the ability to effectively transfer reforming heat load from the radiant section of a reformer to its convection section. The present invention relates a steam methane reformer tube outlet assembly and a method of assembling or retrofitting same. Water enters the furnace, producing steam at a very high temperature. Hydrocarbon steam reforming hydrogen plant, equipment including. Cracking failure analysis of inlet manifold in hydrogen reformer.
Johnson matthey methane and catalyst steam reforming. By using your special skill, the soul alliance, you will beat different enemies, prevent the dark cabals evil, collect souls of monsters or even take them as servants. Bfw is fed through the shell side and becomes 650 psig steam. Johnson matthey process technologies is a leader in reforming technology for the industrial production of hydrogen, methanol and ammonia to the chemicals and oil and gas sectors. Steam reforming takes place in a steam reformer furnace. Abb lummus global its produce ethylene for polymerization with purity 99. The steam methane reforming process can be broken down into five distinct steps. Jaske, creep strength of welds in hydrogen reformer outlet. While performing field welds at bull tee to cone material transitions, cracking was experienced when welding static cast tees 20cr32ni1nb alloy to hot header and reducers cone. Steam reforming is a method for producing hydrogen and carbon dioxide starting from hydrocarbons. The steam reformer represents the core operating unit of most large scale hydrogen production. Learncheme features faculty prepared engineering education resources for students and instructors produced by the department of chemical and biological engineering at the university of colorado boulder and funded by the national science foundation, shell, and the engineering excellence fund. Steam methane reformer furnace outlet manifold component. Refining solutions leverage emersons valves, actuators, regulators, and services to reduce.